Decabromodiphenyl Ethane(DBDPE)

Catalog NumberACM84852539-2

CAS Number84852-53-9

CategoryBrominated Flame Retardant

Description	This product is a new and efficient widely used environment-friendly additive type flame retardant, with advantages of excellent thermal stability, high content of bromine, strong UV-resistance and low toxity, etc. It is widely used in styrenated high polymer, engineering thermolplastics, wires, cable covering, insulator, elastomer and thermoset plastics, etc.
Molecular Weight	971.23
Molecular Formula	C14H4Br10
Appearance	White Powder
Application	Mainly use for styrenated high polymer, engineering thermolplastics, wires, cable covering, insulator, elastomer and thermoset plastics, etc.
Content	Bromine content, 81-82%
Free Bromine	≤5 ppm
Packaging	25kg
Particle Size	≤3/5 μm
Volatiles	≤0.10 %
Whiteness	340

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Case Study

Decabromodiphenyl Ethane/Montmorillonite Synergistic Flame Retardant System for Polypropylene

Chen, Xiao-Sui, et al. Polymer Degradation and Stability, 2009, 94(9), 1520-1525.

Polypropylene/Decabromodiphenyl ethane/antimony trioxide/organic modified montmorillonite (PP/DBDPE/Sb2O3/OMMT) nanocomposites were prepared by melt blending and their combustion performance, thermal stability and char layer morphology were characterized. The results show that the composites containing the modified mixture DBDPE/Sb2O3 can achieve better flame retardancy. In addition, the presence of DBDPE/Sb2O3 can improve the dispersion of OMMT in polypropylene, thereby improving thermal stability and increasing the char residue.
Preparation of the nanocomposites
· Flame retardant particles, including DBDPE, Sb2O3, and OMMT, along with processing additives, were pre-dried at 80°C for 12 hours in a circulating air oven.
· A silane coupling agent was mixed with ethanol in a 1:1 mass ratio. The dried flame retardants DBDPE and Sb2O3 were combined in a 4:1 ratio and thoroughly mixed. They were then surface-modified using various silane coupling agents-such as γ-glycidyloxypropyltrimethoxysilane (GTMS), vinyltrimethoxysilane (VTMS), and γ-aminopropyltrimethoxysilane (APS)-at a concentration of 2 wt% based on the dry weight of the DBDPE/Sb2O3 blend, in a high-speed mixer for 30 minutes.
· After drying, the modified flame retardants were melt-compounded with polypropylene (PP) using a twin-screw extruder at temperatures between 170-180°C for 10-15 minutes. The resulting compounds were then ground into small pieces using a plastic powder pulverizer and molded into bars using an injection molding machine for fire properties testing.

Decabromodiphenylethane/Antimony Trioxide for Flame Retardant Modification of PP Composites

Chen, Xiao-Sui, et al. Journal of applied polymer science, 2013, 127(2), 1446-1453.

Decabromodiphenylethane and antimony trioxide (D-S; the mass ratio of DBDPE to Sb2O3 was 3:1) were introduced as flame retardants to improve the fire resistance of polypropylene/aramid fiber (PP/AF) composites. The results showed that the samples containing 30 wt % D-S and 20 wt % AF achieved V-0 in the UL-94 test. The maximum carbon residue of PP/D-S/AF was as high as 15.5%, which was 115% higher than that of PP/D-S.
Preparation of flame-retardant PP/AF composites
· To eliminate impurities, the AFs were first soaked in a 0.5 wt % sodium hydroxide solution for about 1 hour, followed by immersion in acetone for around 12 hours. They were then dried in an oven at 80°C for 12 hours. The clean, dried fibers were immersed in a 1 wt % phosphate coupling agent solution, mixed with ethanol and water in a 9:1 ratio, for 2 hours. After this, the fibers were dried in an oven at 110°C for 4 hours to create a strong chemical bond between the coupling agent and the AFs, enhancing compatibility with the PP chains.
· The dried, pelletized PP was melt-blended with the modified AFs, D-S, and other processing agents using a twin-screw extruder at temperatures between 160°C and 200°C, with a screw speed of 100 rpm. The mixture was then quenched in a water bath, cut into pellets, and dried in an oven at 80°C for 12 hours. Lastly, the pellets were processed into the desired shapes using a plastic injector at temperatures of 190-200°C for testing mechanical and flammability properties.

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